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1) Identified key species to prepare high-purity a-FePO4 nanoparticles via direct precipitation and explored hydrothermal transformation of various iron phosphate materials. 2) Prepared nano-silica through reversed conversion of silica in HF solution by ammonia cycling for utilizing WPA by-product. 3) Exploited micromixing technology in the preparation of a-FePO4/C nanocomposite via in-situ precipitation for high performance cathode. 4) Synthesized magnetically manipulated polystyrene-based nano-catalyst with good activity and stability quantitatively. |